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This list shows what you get from every NPC in the game. Losing to the NPC may change the outcome of how many wins you need to get your items.

5 wins - card ~ Gunslinger Vorse Raider
9 wins - recipe ~ Roar of The Blue-Eyes White Dragon
14 wins - card ~ King Dragun
18 wins - recipe ~ The Ultimate Dragon
23 wins - card ~ Vampire Lord
27 wins - recipe ~ The Reign of 'Obelisk' & Avatar part (Kaiba's Garms)

KC Dragon (Male) (M)
5 wins - card ~ Horus LV8 & Avatar part (Black Suit)
9 wins - recipe ~ Horus Dragon

frogMaster (Male) (M)
5 wins - card ~ Des Frog & Avatar part (Green Tracksuit)
9 wins - recipe ~ Amphibian Chorus

Sakura (Female) (M)
5 wins - card ~ Sasuke Samurai #4
9 wins - recipe ~ Heads or Tails

Yami Yugi (Male) (S)
5 wins - card ~ Swift Gaia the Fierce Knight
9 wins - recipe ~ Attack of the Ancients
14 wins - card ~ Buster Blader
18 wins - recipe ~ Miracle Magic
23 wins - card ~ Valkyrion the Magna Warrior
27 wins - recipe ~ Slifer the Lightning & Avatar part (Yami Yugi's Garms)

Yami Bakura (Male) (S)
5 wins - card ~ Mask of Darkness
9 wins - recipe ~ The Ouija Board
14 wins - card ~ Puppet Master
18 wins - recipe ~ Spirit Burn!!
23 wins - card ~ Dark Master - Zorc
27 wins - recipe ~ The Ruler of Darkness & Avatar parts (Bakura's Garms, Eye Patch)

Missbomb (Female) (M)
5 wins - card ~ Dark Snake Syndrome & Avatar part (Afro level 1)
9 wins - recipe ~ The Deadly Dark Snake Syndrome

Reia (Female) (M)
5 wins - card ~ Goblin Elite Attack Force
9 wins - recipe ~ Underworld Banquet

ZuruZuru (Male) (M)
5 wins - card ~ Widespread Ruin
9 wins - recipe ~ Mech Soldiers

Joey Wheeler (Male) (S)
5 wins - card ~ Red-Eyes B. Dragon (Grey Background)
9 wins - recipe ~ Wrath of the Black Dragon
14 wins - card ~ Jinzo
18 wins - recipe ~ For the Love of Lady Luck
23 wins - card ~ Graceful Dice
27 wins - recipe ~ Band of Warriors & Avatar part (Joey's Garms)

Yami Marik (Male) (S)
5 wins - card ~ Nightmare's Wheel
9 wins - recipe ~ The Coming of Darkness
14 wins - card ~ Lava Golem
18 wins - recipe ~ An Offering to the Shadows
23 wins - card ~ Zombie Master
27 wins - recipe ~ The Lord of all Winged Dragons & Avatar part (Marik's Garms/Rare Hunter Cloak)

Joker (Male) (M)
5 wins - card ~ Archlord Zerato & Avatar part (Red Tracksuit)
9 wins - recipe ~ Fairys or Fiends

gouk (Male) (M)
5 wins - card ~ Spell Canceller & Avatar part (Sunglasses) & the chance to challenge Seto Kaiba to a duel
9 wins - recipe ~ A World Without Magic

Elly (Female) (M)
5 wins - card ~ Solemn Judgment & The chance to challenge Yami Marik to a duel
9 wins - recipe ~ Infinite Plains

Tea Gardner (Female) (S)
5 wins - card ~ Guardian Angel Joan
9 wins - recipe ~ My Blessings
14 wins - card ~ Voltanis the Adjudicator
18 wins - recipe ~ The Judgment of the Fairys
23 wins - card ~ the sanctuary in the sky
27 wins - recipe ~ The Message From the Skies & Avatar part (Tea's Garms)

Force (Male) (M)
5 wins - card ~ Destiny Hero - Dasher & The chance to challenge Yami Marik to a duel
9 wins - recipe ~ The Forbidden Summon

Robert (Male) (M)
5 wins - card ~ Victory Viper XX03
9 wins - recipe ~ The Legendary Spacecraft

Galum (Male) (M)
5 Wins - card ~ Manju of The Ten Thousand Hands & The chance to challenge Yami Marik to a duel
9 wins - recipe ~ Lumis and Umbra

bankara (Male) (M)
5 wins - card ~ Mobious the Frost Monarch & Avater part (Quiff level 1)
9 wins - recipe ~ 5 Emporers

kyoko (Female) (M)
5 wins - card ~ Brron, Mad King of Dark World & Avatar part (Punk Red)
9 wins - recipe ~ The Dark World Menace

Miss Shadow (Female) (M)
5 wins - card ~ Deck Devastation Virus & Avatar part (Black Suit)
9 wins - recipe ~ Master Disaster

Miss Scout (Female) (M)
5 wins - card ~ Don Zaloog & Avatar part (Sunglasses) & the chance to challenge Seto Kaiba to a duel
9 wins - recipe ~ Dark Scorpion

BeeBee (Male) (M)
5 wins - card ~ Wall of Revealing Light & Avatar part (Red Specs)
9 wins - recipe ~ Winning Without Fighting

kanna (Female) (M)
5 wins - card ~ Destiny Hero Diamond Dude
9 wins - recipe ~ Diamond Draw

Chazz Princeton (Male) (S)
5 wins - card ~ VWXYZ Dragon Catapult Cannon
9 wins - recipe ~ Transform and Combine!!
14 wins - card ~ Armed Dragon LV 7
18 wins - recipe ~ The Dreaded Level Up
23 wins - card ~ Ojama King
27 wins - recipe ~ Ojama Galore! & Avatar part (Chazz's Garms)

Hell Kaiser (Male) (S)
5 wins - card ~ Cyber End Dragon
9 wins - recipe ~ Cyber Dark
14 wins - card ~ Cyberdark Dragon
18 wins - recipe ~ Underworld Deck
23 wins - card ~ Chimeratech Overdragon
27 wins - recipe ~ The Ultimate Cyber Dragon & Avatar part (Kaiser's Garms)

Brow (Male) (M)
5 wins - card ~ Stone Statue of the Aztecs
9 wins - recipe ~ The Iron Curtain

Kyuros (Female) (M)
5 wins - card ~ Compulsory Evacuation Device
9 wins - recipe ~ Monsters Go Home

sabasaba (Male) (M)
5 wins - card ~ Wave Motion Cannon
9 wins - recipe ~ What Good is Defence

Alexis Rhodes (Female) (S)
5 wins - card ~ Etoile Cyber
9 wins - recipe ~ Cyber Girl
14 wins - card ~ Cyber Blader
18 wins - recipe ~ Cyber Girl 2
23 wins - card ~ Advanced Ritual Art
27 wins - recipe ~ Fairies and Archfiends & Avatar part (academy - blue 2)

lalala (Female) (M)
5 wins - card ~ End of Anubis (Chance to Challenge Alexis Rhodes to a Duel)
9 wins - recipe ~ Board of Destiny

raMon (Male) (M)
5 wins - card ~ Emissary of The Afterlife
9 wins - recipe ~ Draw! Draw! Exodia!

Zuno (Male) (M)
5 wins - card ~ Heavy Slump & Avatar part (Steel Blue Tracksuit)
9 wins - recipe ~ The Dreaded Draw

Aster Phoenix (Male) (S)
5 wins - card ~ Elemental Hero Phoenix Enforcer
9 wins - recipe ~ Elemental Heroes Not?!
14 wins - card ~ Destiny Hero - Diamond Dude
18 wins - recipe ~ The Destiny Of Time
23 wins - card ~ Destiny Hero - Dogma
27 wins - recipe ~ Ultimate Destiny Hero & Avatar part (aster's garms)

Queen Ryo (Female) (M)
5 wins - card ~ Brain Control & Avatar part (Brown Glasses)
9 wins - recipe ~ The Wicked Trio

A-lien (Male) (M)
5 wins - card ~ Alien Mother
9 wins - deck recipe ~ Aliens From Outer Space

Kain (Male) (M)
5 wins - card ~ Spell Economics
9 wins - recipe ~ Chaos Cannon!

Jaden Yuki (Male) (S)
5 wins - card ~ Dark Catapulter
9 wins - recipe ~ Elemental Heros On Parade
14 wins - card ~ Elemental Hero Shinning Flare Wingman
18 wins - recipe ~ Solidarity of the Elemental Heros
23 wins - card ~ Elemental Hero Neos
27 wins - recipe ~ New Powers & Avatar part (Jaden's Garms)

Jesse Anderson (Male) (S)
5 wins - card ~ Crystal Beacon
9 wins - recipe ~ Gems and Beasts
14 wins - card ~ Ancient City - Rainbow Ruins
18 wins - recipe ~ A World of Abundance
23 wins - card ~ Crystal Beast Sapphire Pegasus
27 wins - recipe ~ The Gem Lord Cometh! & Avatar part (Jesse's Garms)

Mika (Female) (M)
5 wins - card ~ The Agent of Judgment Saturn & Avatar part (Academy Tracksuit)
9 wins - recipe ~ Judgment of the skies

dancer (Male) (M)
5 wins - card ~ Ultimate Insect LV7 & Avatar part (Afro LV1)
9 wins - recipe ~ The Ultimate Ninja

Abigail (Female) (M)
5 wins - card ~ Elemental Mistress Doraido
9 wins - recipe ~ Mother Nature

NiaNia (Female) (M)
5 wins - card ~ Skull Archfiend of Lightning & Avatar part (pink specs)
9 wins - recipe ~ Archfiend Chess

Rain (Female) (M)
5 wins - card ~ UFO Furtle & Avatar part (Ponytail)
9 wins - recipe ~ Anubis the Gravekeeper

AoJ (Female) (M)
5 wins - card ~ Dimension Wall & the chance to challenge Alexis Rhodes to a duel
9 wins - recipe ~ Hit Me if You Dare